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The methods used for collection of surface-water samples depend not
only on flow characteristics of the surface-water body, but also on the
nature of streamflow, field-measurement profiles, temporal and spatial
homogeneity, physical setting, ecological characteristics, weather
conditions, fluvial-sediment transport, target analytes, point and
nonpoint sources of contamination, and study objectives.
Flowing streamwater is preferably collected using isokinetic depth and
width-integrating sampling methods. Isokinetic depth-integrating methods
are designed to produce a discharge-weighted sample, that is, each unit of
discharge is equally represented in the sample.
Collection of isokinetic, depth-integrated samples involves using
either an equal-width-increment (EWI) or equal-discharge-increment (EDI)
sampling method. EWI or EDI esually results in a composite sample that
represents mean discharge weighted concentrations of the stream
cross-section.
Isokinetic samplers are usually used to obtain a discharge-weighted
sample across a section of flowing water. An isokinetic sampler collects
water so that there is no change in speed and direction as the sample
enters the intake.
The number of verticals to be sampled in order to get a
discharge-weighted sample at a site is related primarily to data
objectives (the accuracy needed) and how well-mixed or homogeneous the
stream is with respect to the physical, chemical, and biological
characteristics (variation) of the cross-section.
In-Situ Measurement of Physical Properties
In-situ measurement of physical properties provides the most accurate
assessment of these characteristics for a given water body because these
properties immediately begin to change once a sample of water is removed
from the water body. Physical properties most commonly measured include:
- Water Temperature
- Specific Conductance
- Dissolved Oxygen
- pH
- Turbidity
- Oxidation-Reduction Potential
Single- or multi-parameter instruments may be used to make in-situ
measurement of physical properties. Many of these instruments also include
data-logging and unattending-monitoring capabilities. Routine maintenance
and careful calibration to known standards are required for accurate
measurements.
Chemical Compatibility of Equipment and the Water Sample
Attention must be given to the materials used to construct the
equipment because these can directly affect sample chemistry. Equipment
designed for water-quality work often is constucted of a combination of
materials, the most inert being for components that will contact the
sample. Materials used in equipment can include plastics, glass, and
metals. Chemical reactivity varies widely within the same group,
depending on the chemical composition, the physical configuration, and the
manufacturing process.
Field personnel must also use techniques to minimize potential
contamination, implement quality-assurance procedures, and quantify
potential effects by using quality-control sample analysis.
Personnel to contact about a specific subject are
listed on the staff page.
U.S. Department of the Interior
U.S. Geological Survey
221 North Broadway, Urbana, IL 61801, USA
URL: http://il.water.usgs.gov/proj/lirb/sw/coll_method/index.html
Maintainer: djfazio@usgs.gov
Last modified: 14:09 CST Thurs 11 May 2000
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